BENJI BENJISAN 50

Chemwatch Independent Material Safety Data Sheet

Issue Date: 25-Jul-2005

NC317TCP

CHEMWATCH 4558-46

Version No:3

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

BENJI BENJISAN 50

PRODUCT USE

Hospital grade disinfectant and deodoriser.

SUPPLIER

Company: Benji Distributors Pty Ltd
Address:
17 Grandview Pde
Moolap
VIC, 3221
Australia
Telephone: +61 3 5248 1469
Fax: +61 3 5248 6696

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.

CHEMWATCH HAZARD RATINGS

Flammability 0
Toxicity 0
Body Contact 3
Reactivity 0
Chronic 0
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

 

RISK SAFETY
■ Causes burns. • Keep locked up.
■ Risk of serious damage to eyes. • Do not breathe gas/ fumes/ vapour/ spray.
• Avoid contact with skin.
• Avoid contact with eyes.
• Wear suitable protective clothing.
• Wear suitable gloves.
• Wear eye/ face protection.
• To clean the floor and all objects contaminated by this material, use water.
• Take off immediately all contaminated clothing.
• In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre.
• In case of accident or if you feel unwell, IMMEDIATELY contact Doctor or Poisons Information Centre (show label if possible).

 

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
quaternary ammonium compound <10
nonionic surfactant <10
alkaline builders <10
fragrance <1
food- grade dye <1
water 7732-18-5 >60^
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.

Section 4 - FIRST AID MEASURES

SWALLOWED

· For advice, contact a Poisons Information Centre or a doctor at once.
· Urgent hospital treatment is likely to be needed.
· If swallowed do NOT induce vomiting.
· If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
· Observe the patient carefully.
· Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
· Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
· Transport to hospital or doctor without delay.

EYE

■ If this product comes in contact with the eyes:
· Immediately hold eyelids apart and flush the eye continuously with running water.
· Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
· Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
· Transport to hospital or doctor without delay.
· Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN

■ If skin or hair contact occurs:
· Immediately flush body and clothes with large amounts of water, using safety shower if available.
· Quickly remove all contaminated clothing, including footwear.
· Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
· Transport to hospital, or doctor.

INHALED

· If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested.
· Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
· Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
· Transport to hospital, or doctor, without delay.

NOTES TO PHYSICIAN

■ Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

· There is no restriction on the type of extinguisher which may be used.
· Use extinguishing media suitable for surrounding area.

FIRE FIGHTING

· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves for fire only.
· Prevent, by any means available, spillage from entering drains or water courses.
· Use fire fighting procedures suitable for surrounding area.
· DO NOT approach containers suspected to be hot.
· Cool fire exposed containers with water spray from a protected location.
· If safe to do so, remove containers from path of fire.
· Equipment should be thoroughly decontaminated after use.

FIRE/EXPLOSION HAZARD

· Non combustible.
· Not considered a significant fire risk, however containers may burn.
May emit corrosive fumes.

FIRE INCOMPATIBILITY

■ None known.

HAZCHEM

None

PERSONAL PROTECTION

Glasses: Gloves:
Full face- shield. 1.BUTYL 2.NEOPRENE 3.VITON

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS

· Clean up all spills immediately.
· Avoid breathing vapours and contact with skin and eyes.
· Control personal contact by using protective equipment.
· Contain and absorb spill with sand, earth, inert material or vermiculite.
· Wipe up.
· Place in a suitable, labelled container for waste disposal.

MAJOR SPILLS

■ Moderate hazard.
· Clear area of personnel and move upwind.
· Alert Fire Brigade and tell them location and nature of hazard.
· Wear breathing apparatus plus protective gloves.
· Prevent, by any means available, spillage from entering drains or water course.
· Stop leak if safe to do so.
· Contain spill with sand, earth or vermiculite.
· Collect recoverable product into labelled containers for recycling.
· Neutralise/decontaminate residue (see Section 13 for specific agent).
· Collect solid residues and seal in labelled drums for disposal.
· Wash area and prevent runoff into drains.
· After clean up operations, decontaminate and launder all protective clothing and equipment before storing
and re- using.
· If contamination of drains or waterways occurs, advise emergency services.

 

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

· Avoid all personal contact, including inhalation.
· Wear protective clothing when risk of exposure occurs.
· Use in a well-ventilated area.
· Avoid contact with moisture.
· Avoid contact with incompatible materials.
· When handling, DO NOT eat, drink or smoke.
· Keep containers securely sealed when not in use.
· Avoid physical damage to containers.
· Always wash hands with soap and water after handling.
· Work clothes should be laundered separately. Launder contaminated clothing before re-use.
· Use good occupational work practice.
· Observe manufacturer's storing and handling recommendations.
· Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
· DO NOT allow clothing wet with material to stay in contact with skin.

SUITABLE CONTAINER

· Polyethylene or polypropylene container.
· Packing as recommended by manufacturer.
· Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY

■ None known.

STORAGE REQUIREMENTS

· Store in original containers.
· Keep containers securely sealed.
· Store in a cool, dry, well-ventilated area.
· Store away from incompatible materials and foodstuff containers.
· Protect containers against physical damage and check regularly for leaks.
· Observe manufacturer's storing and handling recommendations.

_____________________________________________________

SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS

+ + + + X +

_____________________________________________________

+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together

 

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS

• water: CAS:7732-18-5

 

MATERIAL DATA

BENJI BENJISAN 50:
None assigned.

 

PERSONAL PROTECTION

EYE

· Chemical goggles.
· Full face shield may be required for supplementary but never for primary protection of eyes
· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use
and an account of injury experience. Medical and first- aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness
or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS
1336 or national equivalent].

HANDS/FEET

· Wear chemical protective gloves, eg. PVC.
· Wear safety footwear or safety gumboots, eg. Rubber.
· When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

OTHER

· Overalls.
· P.V.C. apron.
· Barrier cream.
· Skin cleansing cream.
· Eye wash unit.
The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information consult
site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.

ENGINEERING CONTROLS

■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well- designed engineering controls can be highly effective
in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard " physically" away from the worker and ventilation that strategically " adds" and "
removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the
particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection.
Supplied- air type respirator may be required in special circumstances. Correct fit is essential to ensure adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area. Air contaminants generated in the workplace possess varying " escape" velocities which, in turn,
determine the " capture velocities" of fresh circulating air required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., evaporating from tank (in still air). 0.25-0.5 m/s (50-100 f/min.)
aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) 0.5-1 m/s (100-200 f/min.)
direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) 1-2.5 m/s (200-500 f/min.)
grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of very high rapid air motion). 2.5-10 m/s (500-2000 f/min.)
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood-local control only
Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1- 2 m/s (200- 400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Clear alkaline liquid with a lemon fragrance; mixes with water.

PHYSICAL PROPERTIES

Liquid.
Mixes with water.

 

StateLiquidMolecular WeightNot applicable
Melting Range (ºC)Not availableViscosityNot Available
Boiling Range (ºC)Not availableSolubility in water (g/L)Miscible
Flash Point (ºC)Not applicablepH (1% solution)Not available
Decomposition Temp (ºC)Not availablepH (as supplied)13
Autoignition Temp (ºC)Not applicableVapour Pressure (kPa)Not available
Upper Explosive Limit (%)Not applicableSpecific Gravity (water=1)1.025
Lower Explosive Limit (%)Not applicableRelative Vapour Density (air=1)Not available
Volatile Component (%vol)Not availableEvaporation RateNot available

 

StateLiquidMolecular WeightNot applicable
Melting Range (ºC)Not availableViscosityNot Available
Boiling Range (ºC)Not availableSolubility in water (g/L)Miscible
Flash Point (ºC)Not applicablepH (1% solution)Not available
Decomposition Temp (ºC)Not availablepH (as supplied)13
Autoignition Temp (ºC)Not applicableVapour Pressure (kPa)Not available
Upper Explosive Limit (%)Not applicableSpecific Gravity (water=1)1.025
Lower Explosive Limit (%)Not applicableRelative Vapour Density (air=1)Not available
Volatile Component (%vol)Not availableEvaporation RateNot available

Section 10 - STABILITY AND REACTIVITY

CONDITIONS CONTRIBUTING TO INSTABILITY

· Presence of incompatible materials.
· Product is considered stable.
· Hazardous polymerisation will not occur.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED

■ The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.
The material has NOT been classified by EC Directives or other classification systems as " harmful by ingestion" . This is because of the lack of corroborating
animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where pre- existing organ (eg. liver,
kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality rather than those producing morbidity
(disease, ill- health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities
is not thought to be cause for concern.

EYE

■ The material can produce chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.
If applied to the eyes, this material causes severe eye damage.

SKIN

■ The material can produce chemical burns following direct contactwith the skin.
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through
wounds, lesions or abrasions.

INHALED

■ The material can cause respiratory irritation in some persons. The body' s response to such irritation can cause further lung damage.
The material has NOT been classified by EC Directives or other classification systems as " harmful by inhalation" . This is because of the lack of corroborating
animal or human evidence. In the absence of such evidence, care should be taken nevertheless to ensure exposure is kept to a minimum and that suitable control
measures be used, in an occupational setting to control vapours, fumes and aerosols.

CHRONIC HEALTH EFFECTS

■ Asthma- like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non- allergenic condition known as reactive
airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include
the absence of preceding respiratory disease, in a non- atopic individual, with abrupt onset of persistent asthma- like symptoms within minutes to hours of a
documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine
challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or
asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance.
Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in
nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production.

TOXICITY AND IRRITATION

BENJI BENJISAN 50:
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
Not available.

 

 

Section 12 - ECOLOGICAL INFORMATION

BENJI BENJISAN 50:
■ DO NOT discharge into sewer or waterways.

Ecotoxicity

IngredientPersistence: Water/SoilPersistence: AirBioaccumulationMobility
Benji Benjisan 50No Data AvailableNo Data Available

 

Section 13 - DISPOSAL CONSIDERATIONS

· Recycle wherever possible.
· Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
· Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or incineration in a licenced apparatus (after admixture with suitable combustible material).
· Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

HAZCHEM:

None (ADG7)
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE S5

REGULATIONS

No data for Benji Benjisan 50 (CW: 4558-46)

Section 16 - OTHER INFORMATION

CONTACT POINT

Paul Milward-Bason
17 Grandview Parade
Moolap 3221
Victoria Australia

 

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.

 

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

 

 

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.

 

Issue Date: 25-Jul-2005

Print Date: 17-Feb-2012

 

 

This is the end of the MSDS.